In situ investigation of degradation at organometal halide perovskite surfaces by X-ray photoelectron spectroscopy at realistic water vapour pressure.

نویسندگان

  • Jack Chun-Ren Ke
  • Alex S Walton
  • David J Lewis
  • Aleksander Tedstone
  • Paul O'Brien
  • Andrew G Thomas
  • Wendy R Flavell
چکیده

Near-ambient-pressure X-ray photoelectron spectroscopy enables the study of the reaction of in situ-prepared methylammonium lead iodide (MAPI) perovskite at realistic water vapour pressures for the first time. We show that MAPI decomposes directly to PbI2, HI and NH3 without formation of methylammonium iodide, allowing us to distinguish between alternative mechanisms for the atmospheric degradation reaction.

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عنوان ژورنال:
  • Chemical communications

دوره 53 37  شماره 

صفحات  -

تاریخ انتشار 2017